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بروف/ أيمن منصور — مستشار الكيمياء
Prof./ Ayman Mansour — Chemistry Consultant
Model 6
Guiding Model 6
كيمياء ٢٠٢٦ — Chemistry 2026
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📋 Answer Key

All 46 Questions

Q1: C
Q2: D
Q3: B
Q4: C
Q5: B
Q6: B
Q7: B
Q8: D
Q9: D
Q10: C
Q11: D
Q12: D
Q13: D
Q14: D
Q15: C
Q16: D
Q17: A
Q18: C
Q19: A
Q20: D
Q21: B
Q22: B
Q23: D
Q24: C
Q25: C
Q26: C
Q27: B
Q28: A
Q29: B
Q30: A
Q31: D
Q32: B
Q33: D
Q34: D
Q35: C
Q36: B
Q37: A
Q38: B
Q39: D
Q40: D
Q41: C
Q42: A
Q43: A
Q44: B
Q45: Essay Q46: Essay

44 MC + 2 Essays

SixthGuiding Model with best explination answer

Chemistry 2026

Complete Examination & Answer Guide

Including:

Full Question Set & Bubble Sheet

Detailed Explanations & Visual Aids

Final Answer Key

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Instructions for Answering

Question 1

Two elements (A, B) from the first transition series, each (A2+, B2+) containing four single electrons and element (A) is less dense than element (B). Which of the following expresses a use for each of (A, B)?
✓ Correct Answer: (c) (A): in leather tanning; (B): in manufacture of surgical tools.
📚 Detailed Explanation

Step 1: Identify the Elements

The prompt states that both A2+ and B2+ ions have 4 unpaired electrons. Let's analyze the 3d configurations:

Possibility 1: 3d4 configuration

This corresponds to Cr2+ (from neutral Cr: [Ar] 4s¹ 3d⁵).

Possibility 2: 3d6 configuration

This corresponds to Fe2+ (from neutral Fe: [Ar] 4s² 3d⁶).

Step 2: Assign A and B based on Density

The prompt also states that element (A) is less dense than element (B).

ElementDensity (g/cm³)
Chromium (Cr)7.19
Iron (Fe)7.87

Therefore, A = Chromium (Cr) and B = Iron (Fe).

Step 3: Match Uses

ElementCommon UseRelevance
A (Cr)Leather TanningChromium(III) sulfate is a key tanning agent.
B (Fe)Surgical ToolsIron is the primary component of stainless steel, used for surgical instruments due to its strength and corrosion resistance.

Comparing with the options, (c) is the correct match.

Question 2

If you know that the elements (X, Y, Z, and W) are transition elements from the first transition series:
W: has the highest magnetic moment in the series
Z: its sublevel (d) is filled with electrons
X: Pairing of electrons in the sublevel (3d) starts after it
Y: is the first element in the series that does not lose all electrons (4s,3d)
Which of the following conversions gives a compound with lower energy?
✓ Correct Answer: (d) X₂O₃ → XO
📚 Detailed Explanation

Step 1: Identify the Elements

SymbolClueAnalysisElement
W Highest magnetic moment Highest number of unpaired electrons (6) in atomic state. Cr ([Ar] 4s¹3d⁵)
Z d-sublevel is filled 3d¹⁰ configuration. Zn ([Ar] 4s²3d¹⁰)
X Pairing starts *after* it The element before 3d⁶ is 3d⁵. Mn ([Ar] 4s²3d⁵)
Y First not to lose all 4s/3d e⁻ Does not show an oxidation state equal to its group number (8). Fe

Step 2: Analyze the Stability of Conversions

A conversion to a "lower energy" compound means forming a more stable product. We check the oxidation states.

OptionConversionOxidation State ChangeStability Analysis
(a)CrO₃ → CrOCr6+ → Cr2+Neither is the most stable state for Cr, which is +3.
(b)ZnO → Zn₂O₃Zn2+ → Zn3+Extremely unfavorable. Zn2+ ([Ar] 3d¹⁰) is very stable.
(c)Fe₂O₃ → FeOFe3+ → Fe2+Unfavorable. Fe3+ has a stable half-filled 3d⁵ configuration.
(d)Mn₂O₃ → MnOMn3+ → Mn2+Highly Favorable. The product Mn2+ has an exceptionally stable half-filled 3d⁵ configuration.
Mn2+: [Ar] 3d⁵ (Lower Energy / More Stable)

Question 3

Three transition elements (A, B, and C):
-The number of unpaired electrons in (A) decreases when it changes from Atomic state to +2 ion.
-The number of single electrons in element (B) increases when it changes from +2 to +3.
- The number of single electrons in element (C) decreases when it changes from +2 to +3, And its radius is equal to that of (A).
Which of the following expresses the correct order of these elements according to their density?
✓ Correct Answer: (b) A < C < B
📚 Detailed Explanation

Step 1: Identify Elements A, B, and C

SymbolClueAnalysisElement
A Unpaired e⁻ ↓ (Atom → +2) Cr (Atom: 6 unpaired e⁻, Cr²⁺: 4 unpaired e⁻) Cr
B Unpaired e⁻ ↑ (+2 → +3) Fe²⁺ (3d⁶, 4 unpaired) → Fe³⁺ (3d⁵, 5 unpaired) Fe
C Unpaired e⁻ ↓ (+2 → +3) and Radius ≈ A Mn²⁺ (3d⁵, 5 unpaired) → Mn³⁺ (3d⁴, 4 unpaired). Radius of Mn (127 pm) ≈ Radius of Cr (128 pm). Mn

Step 2: Order by Density

Density generally increases across a period in the d-block. Let's compare the densities of the identified elements.

LetterElementAtomic NumberDensity (g/cm³)
AChromium (Cr)247.19
CManganese (Mn)257.21
BIron (Fe)267.87

The correct order of increasing density is:

Cr < Mn < Fe
Which corresponds to:
A < C < B

Question 4

(A,B,C and D) Four consecutive transition elements from the first transition series, the electronic distribution of ion (B³⁺) ends with 3d³, Which of the following is correct?
✓ Correct Answer: (c) The magnetic moment of (C) decreases with loss the first electron from the (d) sublevel.
📚 Detailed Explanation

Step 1: Identify Element B and the Sequence

Given: B³⁺ has the configuration [Ar] 3d³. To find the neutral atom B, we add back 3 electrons. They go into the 4s and 3d orbitals.

Neutral B configuration: [Ar] 4s² 3d⁴. This is the expected configuration for Chromium (Cr), Atomic Number 24 (although its actual configuration is anomalous: 4s¹3d⁵).

The four consecutive elements are:

LetterElementAtomic #Actual Config.
AVanadium (V)23[Ar] 4s² 3d³
BChromium (Cr)24[Ar] 4s¹ 3d⁵
CManganese (Mn)25[Ar] 4s² 3d⁵
DIron (Fe)26[Ar] 4s² 3d⁶

Step 2: Evaluate Statement (c)

Statement (c) is about element C = Manganese (Mn). It describes losing "the first electron from the (d) sublevel". This typically refers to the oxidation process from a common ion, in this case Mn²⁺ → Mn³⁺.

SpeciesConfigurationUnpaired ElectronsMagnetic Moment
Mn²⁺[Ar] 3d⁵5High
Mn³⁺ (loses one d-electron)[Ar] 3d⁴4Lower

The number of unpaired electrons decreases from 5 to 4. Since magnetic moment is directly related to the number of unpaired electrons, the magnetic moment decreases. This matches the statement.

Question 5

Which of the following processes causes an increase in the magnetic moment of iron ions in their compounds?
✓ Correct Answer: (b) Heating the compound resulting from adding iron filings to dilute sulphuric acid.
📚 Detailed Explanation

Key Concept: Magnetic Moment of Iron

To increase the magnetic moment, we need to increase the number of unpaired electrons. This means oxidizing Fe²⁺ to Fe³⁺.

Iron IonConfigurationUnpaired ElectronsMagnetic Moment
Fe²⁺[Ar] 3d⁶4Lower
Fe³⁺[Ar] 3d⁵5 (half-filled)Higher

Analyzing the Options:

(a) FeCl₃ + NH₄OH → Fe(OH)₃ → Fe₂O₃: The iron starts as Fe³⁺ and ends as Fe³⁺. No change.

(b) Fe + H₂SO₄ → FeSO₄; then heat:

This process converts Fe²⁺ to Fe³⁺, which increases the magnetic moment. This is the correct answer.

(c) Limonite (Fe₂O₃·nH₂O) heated: Starts as Fe³⁺ and ends as Fe³⁺. No change.

(d) Siderite (FeCO₃) heated in absence of air: FeCO₃ → FeO + CO₂. The iron starts as Fe²⁺ and ends as Fe²⁺. No change.

Question 6

Hydrochloric acid is added to a salt of (X²⁻) anion, a gas (Y) evolves that oxidizes with the normal oxidizing agents. Which of the following applies to the anion (X²⁻) and the gas (Y)?
✓ Correct Answer: (B) Anion: Sulphite / Gas: ...turns acidified K₂Cr₂O₇ green
📚 Detailed Explanation

Step 1: Analyze the Clues

Step 2: Evaluate Remaining Options

Sulphite (SO₃²⁻):

Cr₂O₇²⁻ (Orange) + 3SO₂ + 2H⁺ → 2Cr³⁺ (Green) + 3SO₄²⁻ + H₂O

Sulphide (S²⁻):

Therefore, the only option that fits all criteria is B.

Question 7

Which of the following is not preferred for distinguishing between nitrate and nitrite anions in their salts?
✓ Correct Answer: (b) Hot concentrated sulfuric acid
📚 Detailed Explanation

A good distinguishing test must give a clearly different result for each substance. Let's analyze the reagents:

ReagentReaction with Nitrite (NO₂⁻)Reaction with Nitrate (NO₃⁻)Distinguishing Power
(a) Dilute HCl Reacts to form unstable HNO₂, which decomposes to give brown NO₂ fumes. No reaction. Excellent
(c) Acidified KMnO₄ Decolorizes the purple solution (as it is oxidized). No reaction. Excellent
(d) Brown Ring Test Forms a brown ring immediately. Forms a brown ring upon careful addition of conc. H₂SO₄. The conditions are different enough to distinguish. Good
(b) Hot conc. H₂SO₄ Gives off brown NO₂ fumes. Also gives off brown NO₂ fumes. Poor - Both give similar results, making it difficult to distinguish.

Since hot concentrated sulfuric acid produces brown fumes with both nitrate and nitrite, it is not a preferred method for telling them apart.

Question 8

Add acid (X) to three salts (A, B and C):
-In case of salt (A): a colorless gas evolves, partially oxidized into violet vapors.
-In case of salt (B): a colorless gas evolves, partially oxidized into orange vapors.
-In case of salt (C): a reddish-brown gas evolves.
Which of the following expresses acid (X) and the three salts?
✓ Correct Answer: (D) Acid: Concentrated H₂SO₄; Salts: CaI₂, MgBr₂, Pb(NO₃)₂
📚 Detailed Explanation

The described reactions are characteristic tests for halide and nitrate ions using concentrated sulfuric acid (H₂SO₄).

TestAnionReaction StepsObservation
Salt (A) Iodide (I⁻) from CaI₂ 1. 2I⁻ + H₂SO₄ → 2HI(g) + SO₄²⁻
2. 2HI + H₂SO₄ → I₂(g) + SO₂ + 2H₂O
Colorless HI gas, which oxidizes to violet I₂ vapor.
Salt (B) Bromide (Br⁻) from MgBr₂ 1. 2Br⁻ + H₂SO₄ → 2HBr(g) + SO₄²⁻
2. 2HBr + H₂SO₄ → Br₂(g) + SO₂ + 2H₂O
Colorless HBr gas, which oxidizes to orange-red Br₂ vapor.
Salt (C) Nitrate (NO₃⁻) from Pb(NO₃)₂ 1. 2NO₃⁻ + H₂SO₄ → 2HNO₃ + SO₄²⁻
2. 4HNO₃ → 4NO₂(g) + O₂ + 2H₂O
Initially forms nitric acid, which decomposes on heating to give reddish-brown NO₂ gas.

Therefore, Acid (X) is concentrated H₂SO₄, and the salts contain iodide, bromide, and nitrate ions, matching option (D).

Question 9

From the following diagram, which of the following is correct?
BaCl₂(aq) Y(aq) Precipitate (A) Soluble in diluted acids X(aq) Precipitate (B) Soluble in diluted acids
OptionSolution (X)Precipitation (A)
(a)Na₂SO₄Ba₃(PO₄)₂
(b)Na₂CO₃BaSO₄
(c)Na₂SO₄BaCO₃
(d)Na₂CO₃Ba₃(PO₄)₂
✓ Correct Answer: (d) Solution (X) = Na₂CO₃, Precipitation (A) = Ba₃(PO₄)₂
📚 Detailed Explanation

Step 1: Analyze the Diagram

Barium chloride (BaCl₂) reacts with aqueous solutions X and Y to form two different precipitates (A and B). The crucial clue is that both precipitates are soluble in dilute acids (like HCl).

Step 2: Evaluate Barium Precipitates

Barium SaltFormulaSolubility in Dilute Acid
Barium SulfateBaSO₄Insoluble (White ppt remains)
Barium CarbonateBaCO₃Soluble (Effervescence of CO₂)
Barium PhosphateBa₃(PO₄)₂Soluble (White ppt dissolves)

Step 3: Eliminate Options

Question 10

Two salts (A and B):
- Acid of salt (A) is used to detect cation of salt (B).
- Acid of salt (B) is used to detect anion of salt (A).
Which of the following represents Salt (A) and Salt (B)?
OptionSalt (A)Salt (B)
(a)KClCuSO₄
(b)Hg₂SO₄KCl
(c)KClPbSO₄
(d)K₂SO₄NaNO₃
✓ Correct Answer: (c) Salt (A): KCl / Salt (B): PbSO₄
📚 Detailed Explanation

Step 1: Analyze the Clues

Step 2: Test Option (c)

Let's assign A = KCl and B = PbSO₄.

Salt A is KCl.
The acid of Salt A is Hydrochloric Acid (HCl).
Does HCl detect the cation of Salt B (Pb²⁺)?
Yes! Dilute HCl is the group reagent for Analytical Group I cations (Ag⁺, Pb²⁺, Hg₂²⁺). It reacts to form a white precipitate: Pb²⁺ + 2Cl⁻ → PbCl₂↓

Salt B is PbSO₄.
The acid of Salt B is Sulfuric Acid (H₂SO₄).
Does concentrated H₂SO₄ detect the anion of Salt A (Cl⁻)?
Yes! Concentrated H₂SO₄ is the group reagent for halides. It reacts with solid chlorides to evolve acidic HCl gas: 2KCl + H₂SO₄ → K₂SO₄ + 2HCl↑

Since both conditions hold perfectly, Option (c) is the correct answer.

Question 11

Ammonia is prepared in industry by the Haber-Bosch reaction according to the equation:
N₂(g) + 3H₂(g) ⇌ 2NH₃(g)
Which of the following graphs represents the effect of increasing the partial pressure of nitrogen gas on the previous equilibrium?
(a) Pressure Time H₂ NH₃ N₂ (b) Pressure Time H₂ NH₃ N₂ (c) Pressure Time H₂ NH₃ N₂ (d) Pressure Time H₂ NH₃ N₂
✓ Correct Answer: (d)
📚 Detailed Explanation

Le Chatelier's Principle

When the partial pressure of nitrogen (N₂) is abruptly increased:

  1. Immediate Effect: The concentration/pressure of N₂ undergoes a vertical "spike" at the moment of addition. (This eliminates graph 'c', which shows no spike).
  2. Equilibrium Shift: The system shifts to the right (towards products) to consume the added N₂.
  3. Gradual Changes:
    • N₂ is consumed, so its pressure curves back down (but ends up higher than its original state).
    • H₂ is also consumed as it reacts with the N₂, so its pressure curves downward.
    • NH₃ is produced, so its pressure curves upward.

Graph (d) perfectly illustrates this: a sharp vertical spike in N₂ followed by a gradual decrease, accompanied by a decrease in H₂ and an increase in NH₃.

Question 12

All of the following can express a system at equilibrium state except:
✓ Correct Answer: (d) Obtaining oxygen gas by decomposing hydrogen peroxide
📚 Detailed Explanation

Conditions for Equilibrium

For a chemical or physical equilibrium to exist, the process must be reversible and occur in a system where reactants and products cannot escape (a closed system, or involving species that don't evaporate/precipitate out of the medium entirely).

ProcessReversible?Equilibrium?
(a) Sparingly soluble saltYes (Solid ⇌ Aqueous Ions)Yes
(b) CO₂ in closed containerYes (CO₂(g) ⇌ CO₂(aq))Yes
(c) Acetic acid in waterYes (CH₃COOH ⇌ CH₃COO⁻ + H⁺) - Liquid phase only, open container is fine.Yes
(d) Decomposing H₂O₂No (2H₂O₂ → 2H₂O + O₂↑) - Oxygen gas escapes, preventing the reverse reaction.No

Decomposition of hydrogen peroxide is a highly spontaneous, one-way reaction. The produced oxygen gas escapes, making the process irreversible under normal conditions.

Question 13

The following table shows the pH values of four solutions of different acids with the same concentration:
SolutionpH
A1
B6
C3
The correct order of these solutions according to their ionization constant Ka is:
✓ Correct Answer: (d) A ≻ C ≻ B
📚 Detailed Explanation

Relationship between pH, Acid Strength, and Ka

For acids of the same concentration:

SolutionpHAcid StrengthKa Value
A1StrongestLargest
C3IntermediateMedium
B6WeakestSmallest

Therefore, the order of decreasing Ka is A > C > B.

Question 14

The following balanced reaction at a certain temperature:
2A(aq) + 3B(aq) ⇌ 2C(aq) + 3D(aq)
If the concentrations of the reactants and products at equilibrium are: [A] = 1.5M, [B] = 2.3M, [C] = 3M, [D] = 4.5M
By increasing the concentration of substance (A) and the reaction reaching equilibrium again at the same temperature, then the concentrations at equilibrium become as follows: [A] = 2.5M, [C] = 4M, [D] = 6M.
Which of the following expresses the concentration of substance (B) at equilibrium?
✓ Correct Answer: (d) 2.64 M
📚 Detailed Explanation

Step 1: Calculate the Equilibrium Constant (Kc)

Because the temperature is constant, Kc remains the same before and after adding substance A.

Kc = ([C]² × [D]³) / ([A]² × [B]³)

Using the first set of equilibrium concentrations:

Kc = (3² × 4.5³) / (1.5² × 2.3³) = (9 × 91.125) / (2.25 × 12.167) = 820.125 / 27.37575 ≈ 29.958

Step 2: Solve for the new [B]

Using the new equilibrium concentrations and the same Kc:

29.958 = (4² × 6³) / (2.5² × [B]³)

29.958 = (16 × 216) / (6.25 × [B]³)

29.958 = 3456 / (6.25 × [B]³)

[B]³ = 3456 / (6.25 × 29.958) = 3456 / 187.2375 ≈ 18.458

[B] = ∛18.458 ≈ 2.64 M

Question 15

According to the following balanced reaction: COCl₂(g) ⇌ CO(g) + Cl₂(g)
When a quantity of COCl₂(g) is placed in a closed container with a volume of (1) L, at equilibrium the pressure of Cl₂(g) is equal to (0.3) atm and the total pressure is equal to (0.8) atm, then the value of Kp is:
✓ Correct Answer: (c) 0.45
📚 Detailed Explanation

Step 1: Determine the Partial Pressures

The reaction is: COCl₂(g) ⇌ CO(g) + Cl₂(g)

Because the products CO and Cl₂ are produced in a 1:1 molar ratio from COCl₂, their partial pressures at equilibrium must be equal.

P(Cl₂) = 0.3 atm, therefore P(CO) = 0.3 atm.

Step 2: Find the Pressure of COCl₂

The total pressure is the sum of the partial pressures of all gases:

P(Total) = P(COCl₂) + P(CO) + P(Cl₂)

0.8 atm = P(COCl₂) + 0.3 atm + 0.3 atm

0.8 atm = P(COCl₂) + 0.6 atm

P(COCl₂) = 0.2 atm

Step 3: Calculate Kp

Kp = (P(CO) × P(Cl₂)) / P(COCl₂)

Kp = (0.3 × 0.3) / 0.2 = 0.09 / 0.2 = 0.45

Question 16

Acetic acid solution (X) of 0.1M, diluted by adding water to get a solution (Y) of (0.01M).
Which of the following does not describe solutions (X) and (Y)?
✓ Correct Answer: (d) The ionization constant of acid (X) is higher than that of (Y)

Reasoning: The ionization constant (Ka) is a thermodynamic value that depends only on temperature. Diluting a weak acid changes its degree of ionization (α), hydronium concentration, and pH, but it does NOT change the Ka value. Therefore, Ka of X equals Ka of Y.

Question 17

The reaction that occurs inside an electrochemical cell:
3Cu²⁺ + 2Cr → 3Cu + 2Cr³⁺
knowing that: Cu²⁺ + 2e⁻ → Cu, E° = + 0.340 V
Cr → Cr³⁺ + 3e⁻, E° = + 0.740 V
Which of the following expresses the type of the cell and its emf value?
✓ Correct Answer: (a) Galvanic cell, (+1.08 V) = emf

Step 1: Determine EMF.
The reaction shows Cu²⁺ is reduced (Cathode) and Cr is oxidized (Anode).
Reduction potential of Cu = +0.340 V. Oxidation potential of Cr = +0.740 V.
EMF = E°(oxidation) + E°(reduction) = 0.740 V + 0.340 V = +1.08 V.

Step 2: Determine Cell Type.
Because the EMF is positive, the reaction is spontaneous. A spontaneous electrochemical cell is a Galvanic cell.

Question 18

From the following shapes (four vessels):
Which of the following is correct?
Zn ZnSO4 1 Zn CuSO4 2 Cu ZnSO4 3 Cu CuSO4 4
✓ Correct Answer: (c) When (1) is connected to (4)... electrons spontaneously transfer from (1) to (4).

Connecting vessel (1) [Zn/Zn²⁺] and (4) [Cu/Cu²⁺] creates a classic Daniell cell. Zinc is more active than Copper, so Zinc acts as the anode (oxidation) and Copper acts as the cathode (reduction). Electrons flow through the wire from Anode (Zn, vessel 1) to Cathode (Cu, vessel 4).

Question 19

Two galvanic cells:
The first cell: electrode (X) is the anode, and the hydrogen electrode is the cathode, Giving an emf value of (+0.23) V.
The second cell: electrode (Y) is the cathode and the hydrogen electrode is the anode, Giving an emf value of (+0.8) V.
Which of the following expresses the cell composed of electrodes (X) and (Y)?
✓ Correct Answer: (a) (X) is the anode and (Y) is the cathode, emf = 1.03 V

Correction Note: In the user-provided prompt 'Answer Key', the answer is marked as (C) for 19. Let's recalculate based on standard chemistry.

First cell: X is Anode. E_cell = E_ox(X) + E_red(H) => 0.23 = E_ox(X) + 0. So, Oxidation Potential of X = +0.23 V.

Second cell: Y is Cathode. E_cell = E_ox(H) + E_red(Y) => 0.80 = 0 + E_red(Y). So, Reduction Potential of Y = +0.80 V. (Oxidation Potential of Y = -0.80 V).

Comparing Oxidation Potentials: X (+0.23 V) > Y (-0.80 V).
Because X has a higher oxidation potential, X is the Anode and Y is the Cathode.

EMF = E_ox(Anode) + E_red(Cathode) = 0.23 V + 0.80 V = +1.03 V.

(Thus, statement (a) is chemically correct based on the provided text, despite what a raw key might say. X oxidizes, Y reduces.)

Question 20

The following table shows the oxidation potential of some hypothetical elements:
The elementXYZW
Oxidation potential+ 0.126 V-0.401 V-1.420 V+1.67 V
Which of the following represents the correct protection?
✓ Correct Answer: (d) (Y) Cathodic protection for (X)
📚 Detailed Explanation

Understanding Protection Types

In standard curriculum terminology:

Ordering the Elements by Activity

Higher oxidation potential = More active.

W (+1.67) > X (+0.126) > Y (-0.401) > Z (-1.420)

Evaluating the Options

OptionProposed CoatingActivity ComparisonResult
(a) X Anodic for WCovering W with XX is LESS active than W. (Anodic requires MORE active).False
(b) Z Anodic for YCovering Y with ZZ is LESS active than Y. (Anodic requires MORE active).False
(c) W Cathodic for YCovering Y with WW is MORE active than Y. (Cathodic requires LESS active).False
(d) Y Cathodic for XCovering X with YY is LESS active than X. This creates a successful cathodic coating.True

Question 21

Which of the following expresses the reaction that occurs at the anode of an electrolytic cell for molten potassium bromide?
✓ Correct Answer: (b) 2Br⁻ → Br₂ + 2e⁻

Reasoning: In an electrolytic cell, the Anode is the positive electrode where Oxidation (loss of electrons) takes place.

Molten potassium bromide (KBr) contains K⁺ and Br⁻ ions.

Question 22

Which of the following is correct for negative hydroxide ions in a fuel cell?
✓ Correct Answer: (b) Consumed as a result of the oxidation reaction and formed as a result of the Reduction reaction.

In a Hydrogen-Oxygen fuel cell (alkaline type), the electrolyte is typically hot aqueous KOH. Let's look at the half-reactions:

Anode (Oxidation): 2H₂(g) + 4OH⁻(aq) → 4H₂O(l) + 4e⁻
Here, OH⁻ ions are consumed.

Cathode (Reduction): O₂(g) + 2H₂O(l) + 4e⁻ → 4OH⁻(aq)
Here, OH⁻ ions are formed.

Therefore, the hydroxide ions migrate from the cathode to the anode, being produced at the cathode (reduction site) and used up at the anode (oxidation site).

Question 23

Compounds (X and Y) are hydrocarbon derivatives where:
(X): is produced from the chlorination of the compound resulting from the dry Distillation of sodium acetate by replacing three hydrogen atoms
(Y): is produced from the dehydration of 2-chloroethanol at 180°C.
Which of the following represents (X or Y)?
✓ Correct Answer: (d) (Y): Alkene derivative used as a raw material in the manufacture of water hoses
📚 Detailed Explanation

Step 1: Identify Compound X

Dry distillation of sodium acetate with soda lime produces Methane:

CH₃COONa + NaOH --(heat)→ CH₄ + Na₂CO₃

Chlorinating Methane by replacing three hydrogen atoms yields Chloroform (CHCl₃):

CH₄ + 3Cl₂ → CHCl₃ + 3HCl

Properties of X: Chloroform is a substituted alkane. It was historically used as an anesthetic.

Step 2: Identify Compound Y

Dehydration of 2-chloroethanol (Cl-CH₂-CH₂-OH) at 180°C removes H and OH to form a double bond:

Cl-CH₂-CH₂-OH --(H₂SO₄, 180°C)→ CH₂=CH-Cl + H₂O

Properties of Y: The product is Vinyl Chloride (chloroethene). It is an alkene derivative used as the monomer to make PVC (Polyvinyl Chloride), which is used in water hoses and pipes. This makes option (d) true regarding compound Y,

Question 24

Which of the following compounds burns completely to produce (5) moles of CO₂ and (5) moles of water vapor?
✓ Correct Answer: (C) 1,1- dimethyl cyclo propane

Step 1: Determine the molecular formula.
Combustion of a hydrocarbon CxHy produces x moles of CO₂ and y/2 moles of H₂O.
If 5 moles of CO₂ are produced, x = 5 (Carbon atoms = 5).
If 5 moles of H₂O are produced, y/2 = 5 → y = 10 (Hydrogen atoms = 10).
The required molecular formula is C₅H₁₀.

Step 2: Check the options.

CompoundClassFormula
2-methyl butaneAlkane (CₙH₂ₙ₊₂)C₅H₁₂
2,2- dimethyl -2-buteneAlkene (CₙH₂ₙ)C₆H₁₂ (6 Carbons!)
1,1- dimethyl cyclo propaneCycloalkane (CₙH₂ₙ)C₅H₁₀
2-pentyneAlkyne (CₙH₂ₙ₋₂)C₅H₈

Question 25

(X and Y) are two isomers of the formula C₄H₈O with different functional groups.
If (X) turns acidified potassium dichromate to green, while (Y) has no effect on Acidified potassium dichromate.
Which of the following represents (X) or (Y)?
✓ Correct Answer: (c) X: 2-methyl propanal.

Chemical Analysis: The formula C₄H₈O corresponds to an aldehyde or a ketone.

Question 26

The corresponding structure of one of polymers:
—[ CH₂ — CH(C₂H₅) ]ₙ—
Which of the following expresses the monomer properties of this polymer?
✓ Correct Answer: (c) It reacts with catalytic hydration to give 2-butanol.
📚 Detailed Explanation

Step 1: Identify the Monomer

The repeating unit of the polymer is —CH₂—CH(C₂H₅)—. To find the monomer, we restore the double bond between the two carbon atoms of the backbone.

Monomer: CH₂ = CH — CH₂ — CH₃
Name: 1-Butene

Step 2: Evaluate the Reactions of 1-Butene

1-Butene is an unsymmetrical alkene, so its addition reactions follow Markovnikov's Rule (the hydrogen adds to the carbon with more hydrogens in case of addition of asymmetric reagents only not all addition reactions).

ReactionEquationProductEvaluation
(b) + HBr CH₂=CH-CH₂CH₃ + HBr → CH₃-CHBr-CH₂CH₃ 2-bromobutane Option says 1-bromobutane. (False)
(c) Hydration (+ H₂O/H⁺) CH₂=CH-CH₂CH₃ + H₂O → CH₃-CH(OH)-CH₂CH₃ 2-butanol True!
(d) + Br₂ CH₂=CH-CH₂CH₃ + Br₂ → CH₂Br-CHBr-CH₂CH₃ 1,2-dibromobutane Option says 2,2-dibromo. (False)

Question 27

Three organic compounds:
(A) : C₂H₄O
(B) : C₂H₆O
(C) : C₂H₄
Which of the following is correct?
✓ Correct Answer: (b) Oxidation of both (A, B) produces an acid used in the manufacture of insecticides.

Identify Compounds:

Analyze Oxidation:
Oxidation of Acetaldehyde (A) yields Acetic acid (Ethanoic acid).
Oxidation of Ethanol (B) yields Acetaldehyde, then Acetic acid.
Acetic acid is a well-known raw material used in the chemical industry for the manufacture of dyes, plastics, and insecticides.

Question 28

A compound has the molecular formula: C₇H₇NO
Which of the following esters can be used to prepare that compound?
✓ Correct Answer: (a) C₆H₅COOCH₃

The compound with the formula C₇H₇NO is Benzamide (C₆H₅CONH₂). Count the atoms: C: 6+1=7, H: 5+2=7, N: 1, O: 1.

Amides not ester are prepared by the ammonolysis of esters (reacting an ester with ammonia).

C₆H₅COOCH₃ + NH₃ → C₆H₅CONH₂ + CH₃OH

Reacting Methyl benzoate (Option A) with ammonia perfectly yields Benzamide and Methanol.

Question 29

(X, Y and Z) are three hydrocarbon derivatives have the following molecular Formulas:
(X): CH₂O
(Y): C₂H₆O
(Z): C₂H₆O₂
Which of the following represents (X, Y and Z)?
Option(X)(Y)(Z)
a)KetoneAliphatic EtherPrimary dihydric alcohol
b)AldehydePrimary monohydric alcoholPrimary dihydric alcohol
c)Carboxylic acidMonohydric secondary alcoholAliphatic ester
d)AldehydeAliphatic EtherCarboxylic acid
✓ Correct Answer: (b)

Match formulas to functional groups:

Option B aligns perfectly with these structures.

Question 30

Three organic compounds (A, B and C):
- When adding excess of NaOH to the three compounds: (B) Consumes quantity of NaOH double that consumed by (A). (C) doesn’t react.
- When heating (A) with (C), the produced compound is used as a flavor.
Which of the following represents compounds (A), (B), and (C)?
✓ Correct Answer: (a) (A): C₃H₆O₃, (B): C₇H₆O₃, (C): C₂H₆O

Step 1: Identify C
Compound C does not react with NaOH, but it reacts with A to form a flavor (an ester). This means C is an alcohol. C₂H₆O is Ethanol.

Step 2: Identify A and B based on NaOH consumption

Since B consumes double the quantity of A, B is Salicylic acid (C₇H₆O₃) and A is Lactic acid (C₃H₆O₃). Heating A (Lactic acid) with C (Ethanol) produces Ethyl lactate, an ester used as a flavoring agent.

Question 31

The following table shows the molecular formulas of organic compounds:
ABC
C₃H₈O₃C₃H₈O₂C₂H₄O₂
Which of the following represents the correct order of the compounds (C, B, A) according to boiling point?
✓ Correct Answer: (d) A > B > C
📚 Detailed Explanation

The boiling point of organic compounds with hydroxyl (-OH) groups is primarily determined by the extent of hydrogen bonding. More -OH groups mean stronger intermolecular forces.

CompoundLikely Identity-OH GroupsBoiling Point
A (C₃H₈O₃)Glycerol (trihydric alcohol)3Highest (~290°C)
B (C₃H₈O₂)Propylene glycol (dihydric alcohol)2Middle (~188°C)
C (C₂H₄O₂)Acetic acid (monocarboxylic)1 (-COOH)Lowest (~118°C) ,both B&C have same number of hydrogen bonds but molecular weightof B is higher so B has higher boiling point

Therefore, the correct decreasing order is A > B > C.

Question 32

Which of the following is the correct IUPAC name for the product of hydrolysis of the compound C₆H₅OOCCH₃ in an acidic medium?
✓ Correct Answer: (b) Ethanoic acid and phenol

The compound C₆H₅OOCCH₃ is an ester. Specifically, it is formed from the acetate (ethanoate) radical CH₃COO- and the phenyl radical -C₆H₅. Its common name is phenyl acetate.

Acidic hydrolysis of an ester breaks it back down into its constituent carboxylic acid and alcohol/phenol:

CH₃COOC₆H₅ + H₂O --(H⁺)→ CH₃COOH + C₆H₅OH

The IUPAC name for CH₃COOH is Ethanoic acid. The IUPAC accepted name for C₆H₅OH is Phenol. (While "acetic acid" and "hydroxybenzene" are valid names, "ethanoic acid" and "phenol" perfectly fit standard IUPAC multiple-choice criteria here).

Question 33

(Y, X) are two consecutive transition elements in the first transition series, each of them has a compound in its highest oxidation state act as an oxidizing agent.
Which of the following is correct?
✓ Correct Answer: (d) The alloy consisting of the two elements between which (X and Y) are located With carbon is characterized by hardness.
📚 Detailed Explanation

Step 1: Identify X and Y.
1. Identify elements $X$ and $Y$: * The question states that $X$ and $Y$ are two consecutive transition elements in the first transition series, and each has a compound in its highest oxidation state that acts as an oxidizing agent. * Chromium ($\text{Cr}$, $Z = 24$): Its highest oxidation state is $+6$, found in potassium dichromate ($\text{K}_2\text{Cr}_2\text{O}_7$), which is a well-known strong oxidizing agent. * Manganese ($\text{Mn}$, $Z = 25$): Its highest oxidation state is $+7$, found in potassium permanganate ($\text{KMnO}_4$), which is also a powerful oxidizing agent. * Therefore, $X$ and $Y$ are $\text{Cr}$ and $\text{Mn}$.

Step 2: Evaluate the uses.
If we let Y = Cr(V2O5) and Mn = Mn (or vice versa):

Question 34

(12 g) of a mixture of sodium phosphate and potassium iodide is dissolved in water and excess of silver nitrate solution is added to it, forming a yellow precipitate with a mass of (X g). Then, an excess of ammonium hydroxide solution is added, leaving a precipitate with a mass of (8.5 g).
Which of the following expresses the mass of the precipitate (X)?
(Ag=108, K=39, Na=23, I=127, P=31, O=16, N=14)
✓ Correct Answer: (d) 23.82g

1. Identify the precipitates: AgNO₃ forms Ag₃PO₄ (yellow, soluble in NH₄OH) and AgI (yellow, insoluble in NH₄OH).

2. Mass of AgI: Since excess NH₄OH dissolves the Ag₃PO₄, the remaining 8.5g is entirely AgI.
Moles of AgI = 8.5g / (108+127)g/mol = 8.5 / 235 = 0.03617 mol.

3. Find KI mass in mixture: Moles KI = Moles AgI = 0.03617 mol.
Mass KI = 0.03617 × (39+127) = 0.03617 × 166 = 6.00 g.

4. Find Na₃PO₄ mass: Total mixture = 12g. Mass Na₃PO₄ = 12g - 6g = 6.00 g.
Moles Na₃PO₄ = 6.00 / (23×3 + 31 + 16×4) = 6.00 / 164 = 0.03658 mol.

5. Find Ag₃PO₄ mass: Moles Ag₃PO₄ = Moles Na₃PO₄ = 0.03658 mol.
Mass Ag₃PO₄ = 0.03658 × (108×3 + 31 + 16×4) = 0.03658 × 419 = 15.32 g.

6. Total initial yellow precipitate (X): Mass AgI + Mass Ag₃PO₄ = 8.5g + 15.32g = 23.82 g.

Question 35

If you know that (16 mL) of potassium hydroxide solution is needed to titrate (32 mL) of sulphuric acid.
Which of the following expresses the concentration of sulphuric acid?
✓ Correct Answer: (c) Quarter The concentration of potassium hydroxide
📚 Detailed Explanation

Step 1: Write the balanced chemical equation.

H₂SO₄ + 2KOH → K₂SO₄ + 2H₂O

From the equation, 1 mole of acid reacts with 2 moles of base (nₐ = 1, n_b = 2).

Step 2: Use the titration formula.

(Mₐ × Vₐ) / nₐ = (M_b × V_b) / n_b

(Mₐ × 32) / 1 = (M_b × 16) / 2

32 Mₐ = 8 M_b

Mₐ = (8 / 32) M_b = ¼ M_b

Therefore, the concentration of the sulphuric acid is a quarter of the concentration of the potassium hydroxide.

Question 36

If you know that the solubility of magnesium carbonate MgCO₃ in water at a temperature of 25ºC is equal to (4.4 X 10⁻⁵ mol / 100 mL), then the solubility product (Ksp) of this salt is equal to:
✓ Correct Answer: (b) 1.9 x 10⁻⁷

Step 1: Convert solubility to Molarity (mol/L).
Solubility given = 4.4 × 10⁻⁵ mol / 100 mL.
To find mol / 1000 mL (1 Liter), multiply by 10:
Molar Solubility (s) = 4.4 × 10⁻⁴ mol/L.

Step 2: Write the dissociation equation and Ksp expression.
MgCO₃(s) ⇌ Mg²⁺(aq) + CO₃²⁻(aq)
Ksp = [Mg²⁺][CO₃²⁻] = (s)(s) = .

Step 3: Calculate Ksp.
Ksp = (4.4 × 10⁻⁴)² = 19.36 × 10⁻⁸ = 1.936 × 10⁻⁷.

Question 37

When (0.8) moles of substance (A) are placed in a (1L) and equilibrium is reached according to the following equation: A(aq) ⇌ 2B
It is found that (0.4) moles of substance (A) are converted to (B).
Which of the following represents the equilibrium state and equilibrium constant for this reaction?
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 (b) Kc=0.4 Concentration (Mol/L) Time A B (a) Kc=1.6 Concentration (Mol/L) Time A B (d) Kc=1.6 Concentration (Mol/L) Time A B (c) Kc=1 Concentration (Mol/L) Time A B
✓ Correct Answer: (a) Graph showing A stabilizing at 0.4 and B stabilizing at 0.8, Kc = 1.6
📚 Detailed Explanation

Step 1: ICE Table (Initial, Change, Equilibrium)

Species[A][B]
Initial (M)0.80
Change (M)-0.4 (Given)+ (2 × 0.4) = +0.8
Equilibrium (M)0.40.8

The graph must show reactant [A] starting at 0.8 and dropping to level off at 0.4. Product [B] must start at 0 and rise to level off at 0.8. (Graph B illustrates this perfectly).

Step 2: Calculate Kc

Kc = [B]² / [A]

Kc = (0.8)² / (0.4) = 0.64 / 0.4 = 1.6.

Question 38

The amount of electricity required to precipitate (1 mol) of Au³⁺ can precipitate (1.5 mol) of:
✓ Correct Answer: (b) Mg²⁺
📚 Detailed Explanation

Step 1: Electricity for Gold
Reaction: Au³⁺ + 3e⁻ → Au
To precipitate 1 mole of Au, we need 3 moles of electrons (3 Faradays).

Step 2: Determine valence of unknown metal
We have 3 Faradays of electricity available. We want to know which ion will yield 1.5 moles of precipitate with these 3 Faradays.
Moles of metal = (Faradays) / (Valence charge z)
1.5 = 3 / z
z = 3 / 1.5 = 2.

The unknown ion must have a +2 charge. Looking at the options, only Mg²⁺ is divalent (+2).

Question 39

Permanganate ions MnO₄⁻ can be prepared by electrolysis of a solution containing manganese ions Mn²⁺ according to the following reaction:
Mn²⁺ + 4 H₂O → MnO₄⁻ + 8H⁺ + 5e⁻
The amount of electricity required to prepare 0.2 mol of permanganate ions is equal to:
✓ Correct Answer: (d) 96500 C

From the balanced half-reaction, producing 1 mole of MnO₄⁻ requires 5 moles of electrons (5 Faradays).

To produce 0.2 moles of MnO₄⁻, the moles of electrons required = 0.2 × 5 = 1 mole of electrons (1 Faraday).

We know that 1 Faraday is equal to 96500 Coulombs (C). Therefore, the required electricity is 96500 C.

Question 40

Three organic compounds with the molecular formula C₃H₈O
(X): Decolorizes acidified KMnO₄ solution and forms a compound That reacts with sodium carbonate.
(Y): Decolorizes acidified KMnO₄ solution and forms a compound That does not respond to acidity test.
(Z): Does not decolorize acidified KMnO₄ solution.
Which of the following expresses the number of methyl groups in each of (X, Y and Z)?
Option(X)(Y)(Z)
A102
B212
C221
D122
✓ Correct Answer: (D) X=1, Y=2, Z=2
📚 Detailed Explanation

The formula C₃H₈O represents saturated alcohols and ethers. Let's analyze the clues:

This perfectly aligns with Option D: 1, 2, 2.

Question 41

(A) and (B) are hydroxyl organic compounds, the (O-H) bond in compound (A) is Longer and weaker than that in compound (B). Which of the following is correct?
✓ Correct Answer: (c) (A) reacts with sodium hydroxide while (B) does not react

A "longer and weaker" O-H bond means the hydrogen is more easily lost as an H⁺ ion, indicating stronger acidity. In organic chemistry, phenols are more acidic than aliphatic alcohols because the benzene ring withdraws electron density, weakening the O-H bond.

Therefore, (A) is a Phenol and (B) is an Alcohol.

Question 42

From the following diagram: Dry distillation Thermal cracking + Simplest alkene Catalytic reforming Hydrogenation Sodium deaconate X Y Z M W
Which of the following describes compound (M)?
✓ Correct Answer: (A) (M): Saturated cyclic hydrocarbon, W: Oxidizes to an aromatic acid
📚 Detailed Explanation

Step 1: Trace the reactions.

Step 2: Evaluate compound properties.

M (Methylcyclohexane) is a saturated cyclic hydrocarbon (but NOT cyclohexane exactly, making B incorrect).
W (Toluene) oxidizes with KMnO₄ to form Benzoic acid (an aromatic acid).

Option A perfectly describes the families of these compounds.

Question 43

Three organic acids (A, B, C):
(A): Produced by the reaction of a 3 moles of caustic soda with 1 mole of 1,1,1-Trichloroethane.
(B): Produced by the fermentation of lactose in milk by certain types of bacteria.
(C): Reacts with methanol to form a substance used to remove rheumatic pain.
Which of the following represents the above acids?
✓ Correct Answer: (a) A=C₂H₄O₂, B=C₃H₆O₃, C=C₇H₆O₃
📚 Detailed Explanation

Question 44

(X and Y) are carboxylic acids with the following molecular formulas:
(X): (C₇H₆O₃)
(Y): (C₃H₆O₃)
Which of the following expresses the reaction of one mole of (X and Y) with the substances listed in the table? (Moles required)
OptionNaOH for (Y)NaOH for (X)Na for (Y)Na for (X)
a1111
b1222
c2212
d2222
✓ Correct Answer: (b)

Salicylic Acid (X): Contains 1 Carboxyl group (-COOH) and 1 Phenolic group (-OH).
- NaOH reacts with BOTH (acids and phenols). Needs 2 moles.
- Na metal reacts with BOTH. Needs 2 moles.

Lactic Acid (Y): Contains 1 Carboxyl group (-COOH) and 1 Aliphatic Alcohol group (-OH).
- NaOH reacts ONLY with the acid group. Needs 1 mole.
- Na metal reacts with BOTH acid and alcohol groups. Needs 2 moles.

Question 45

Question 45: Given the following diagram: After a period of time in air Process (1) NaOH Process (2) Process (3) CO / 400°C : 700°C O₂ / Δ Dil. / HCl Conc. H₂SO₄ A B C D E F
(1) Write the chemical formulas for (F, B).
(2) What is the name of process (3)?
Answers to 45:
1) F = FeCl2 (Iron II Chloride), B = Fe2(SO₄)3 (Magnetic III Sulfate).
2) Process (3) is heating.

Question 46

Question 46: From the following diagram (knowing C & B are isomers): Hydrolysis + Process (1) H₂SO₄ (180°C) H₂SO₄ (140°C) A B C Y D (X)
1- Write the chemical formulas for (X) and (C).
2- Name process number (1).
Answers to 46:
1)Sucrose (A) hydrolysis yields Glucose and Fructose (isomers). Fermentation of Glucose (D) yields Ethanol(D).
2)Since D reacts at 140°C to form an ether (X) and at 180°C to form an alkene (Y), D must be an alcohol (EthanoL).
3) Process 1 is Biological process is Fermentation.

Chemistry Breakdown for 46:
Sucrose (A) hydrolysis yields Glucose and Fructose (isomers). Fermentation of Glucose (B) yields Ethanol(D).
Ethanol (D) + H₂SO₄ at 180°C → Ethene (Y).
Ethanol (D) + H₂SO₄ at 140°C → Diethyl ether (X).

Sixth Guiding Model & answer

📋 Answer Key - Bubble Sheet

✓ Model Answers for All Questions

44 Multiple Choice + 2 Essay Questions

Questions 1-23

Q A B C D
Q1
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Questions 24-46

Q A B C D
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Q45ESSAY QUESTION
Q46ESSAY QUESTION

Total Score: ((1:32)x1M =32M +(33:42)x2M =24M MCQ ) = 56M + 2 Essay x2M = 4M total 56+4=60M

Filled circle = Correct Answer | Empty circle = Incorrect Option

📋 Answer Key - Bubble Sheet

✓ Model Answers for All Questions

44 Multiple Choice + 2 Essay Questions

Questions 1-23

Q A B C D
Q1
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Questions 24-46

Q A B C D
Q24
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Q45ESSAY QUESTION
Q46ESSAY QUESTION

Total Score: 44 MCQ × 2.5 pts = 110 points + 2 Essays = 40 points

● = Correct Answer | ☐ = Incorrect Option

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بروف/ أيمن منصور — مستشار الكيمياء| Prof./ Ayman Mansour — Chemistry Consultant| 📞 / WhatsApp: 01068018005 · 01287996430| كيمياء ٢٠٢٦ • Chemistry 2026
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